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Crystal and molecular structures of some phosphane-substituted cymantrenes [(C(5)H(4) X)Mn(CO)LL′] (X = H or Cl, L = CO, L′ = PPh(3) or PCy(3), and LL’ = Ph(2)PCH(2)CH(2)PPh(2))
UV irradiation of tetrahydrofuran solutions of [CpMn(CO)(3)] (Cp = π-C(5)H(5) or π-C(5)H(4)Cl) in the presence of the phosphanes PPh(3) or PCy(3) (Cy = cyclohexyl) and Ph(2)PCH(2)CH(2)PPh(2) yields the substitution products [CpMn(CO)(2)PR (3)] (R = Ph or Cy) and [CpMn(CO)(Ph(2)PCH(2)CH(2)PPh(2))...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491095/ https://www.ncbi.nlm.nih.gov/pubmed/34607986 http://dx.doi.org/10.1107/S2053229621009177 |