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Crystal and mol­ecular structures of some phosphane-substituted cymantrenes [(C(5)H(4) X)Mn(CO)LL′] (X = H or Cl, L = CO, L′ = PPh(3) or PCy(3), and LL’ = Ph(2)PCH(2)CH(2)PPh(2))

UV irradiation of tetra­hydro­furan solutions of [CpMn(CO)(3)] (Cp = π-C(5)H(5) or π-C(5)H(4)Cl) in the presence of the phosphanes PPh(3) or PCy(3) (Cy = cyclo­hex­yl) and Ph(2)PCH(2)CH(2)PPh(2) yields the substitution products [CpMn(CO)(2)PR (3)] (R = Ph or Cy) and [CpMn(CO)(Ph(2)PCH(2)CH(2)PPh(2))...

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Detalles Bibliográficos
Autores principales: Sünkel, Karlheinz, Klein-Hessling, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8491095/
https://www.ncbi.nlm.nih.gov/pubmed/34607986
http://dx.doi.org/10.1107/S2053229621009177