Scaffold-based [Fe]-hydrogenase model: H(2) activation initiates Fe(0)-hydride extrusion and non-biomimetic hydride transfer

We report the synthesis and reactivity of a model of [Fe]-hydrogenase derived from an anthracene-based scaffold that includes the endogenous, organometallic acyl(methylene) donor. In comparison to other non-scaffolded acyl-containing complexes, the complex described herein retains molecularly well-d...

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Detalles Bibliográficos
Autores principales: Kerns, Spencer A., Seo, Junhyeok, Lynch, Vincent M., Shearer, Jason, Goralski, Sean T., Sullivan, Eileen R., Rose, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8494020/
https://www.ncbi.nlm.nih.gov/pubmed/34703571
http://dx.doi.org/10.1039/d0sc03154b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8494020/
https://www.ncbi.nlm.nih.gov/pubmed/34703571
http://dx.doi.org/10.1039/d0sc03154b

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