Characterization and chemical reactivity of room-temperature-stable Mn(III)–alkylperoxo complexes

While alkylperoxomanganese(iii) (Mn(III)–OOR) intermediates are proposed in the catalytic cycles of several manganese-dependent enzymes, their characterization has proven to be a challenge due to their inherent thermal instability. Fundamental understanding of the structural and electronic propertie...

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Detalles Bibliográficos
Autores principales: Opalade, Adedamola A., Parham, Joshua D., Day, Victor W., Jackson, Timothy A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8494025/
https://www.ncbi.nlm.nih.gov/pubmed/34703542
http://dx.doi.org/10.1039/d1sc01976g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8494025/
https://www.ncbi.nlm.nih.gov/pubmed/34703542
http://dx.doi.org/10.1039/d1sc01976g

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