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Characterization and chemical reactivity of room-temperature-stable Mn(III)–alkylperoxo complexes
While alkylperoxomanganese(iii) (Mn(III)–OOR) intermediates are proposed in the catalytic cycles of several manganese-dependent enzymes, their characterization has proven to be a challenge due to their inherent thermal instability. Fundamental understanding of the structural and electronic propertie...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8494025/ https://www.ncbi.nlm.nih.gov/pubmed/34703542 http://dx.doi.org/10.1039/d1sc01976g |