Modelling local structural and electronic consequences of proton and hydrogen-atom uptake in VO(2) with polyoxovanadate clusters

We report the synthesis and characterisation of a series of siloxide-functionalised polyoxovanadate–alkoxide (POV–alkoxide) clusters, [V(6)O(6)(OSiMe(3))(OMe)(12)](n) (n = 1−, 2−), that serve as molecular models for proton and hydrogen-atom uptake in vanadium dioxide, respectively. Installation of a...

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Detalles Bibliográficos
Autores principales: Chakraborty, Sourav, Schreiber, Eric, Sanchez-Lievanos, Karla R., Tariq, Mehrin, Brennessel, William W., Knowles, Kathryn E., Matson, Ellen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8494032/
https://www.ncbi.nlm.nih.gov/pubmed/34703561
http://dx.doi.org/10.1039/d1sc02809j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8494032/
https://www.ncbi.nlm.nih.gov/pubmed/34703561
http://dx.doi.org/10.1039/d1sc02809j

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