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Modelling local structural and electronic consequences of proton and hydrogen-atom uptake in VO(2) with polyoxovanadate clusters
We report the synthesis and characterisation of a series of siloxide-functionalised polyoxovanadate–alkoxide (POV–alkoxide) clusters, [V(6)O(6)(OSiMe(3))(OMe)(12)](n) (n = 1−, 2−), that serve as molecular models for proton and hydrogen-atom uptake in vanadium dioxide, respectively. Installation of a...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8494032/ https://www.ncbi.nlm.nih.gov/pubmed/34703561 http://dx.doi.org/10.1039/d1sc02809j |