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Nitride protonation and NH(3) binding versus N–H bond cleavage in uranium nitrides

The conversion of metal nitrides to NH(3) is an essential step in dinitrogen fixation, but there is limited knowledge of the reactivity of nitrides with protons (H(+)). Herein, we report comparative studies for the reactions of H(+) and NH(3) with uranium nitrides, containing different types of anci...

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Detalles Bibliográficos
Autores principales: Keener, Megan, Scopelliti, Rosario, Mazzanti, Marinella
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8494049/
https://www.ncbi.nlm.nih.gov/pubmed/34703546
http://dx.doi.org/10.1039/d1sc03957a