A homoleptic alkynyl-protected [Ag(9)Cu(6)((t)BuC[triple bond, length as m-dash]C)(12)](+) superatom with free electrons: synthesis, structure analysis, and different properties compared with the Au(7)Ag(8) cluster in the M(15)(+) series

We report the first homoleptic alkynyl-protected AgCu superatomic nanocluster [Ag(9)Cu(6)((t)BuC[triple bond, length as m-dash]C)(12)](+) (NC 1, also Ag(9)Cu(6) in short), which has a body-centered-cubic structure with a Ag(1)@Ag(8)@Cu(6) metal core. Such a configuration is reminiscent of the report...

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Detalles Bibliográficos
Autores principales: Ma, Xiaoshuang, Xiong, Lin, Qin, Lubing, Tang, Yun, Ma, Guanyu, Pei, Yong, Tang, Zhenghua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8494057/
https://www.ncbi.nlm.nih.gov/pubmed/34703569
http://dx.doi.org/10.1039/d1sc03679c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8494057/
https://www.ncbi.nlm.nih.gov/pubmed/34703569
http://dx.doi.org/10.1039/d1sc03679c

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