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Phosphirenium Ions as Masked Phosphenium Catalysts: Mechanistic Evaluation and Application in Synthesis

[Image: see text] The utilization of phosphirenium ions is presented; optimized and broadened three-membered ring construction is described together with the use of these ions as efficient pre-catalysts for metal-free carbonyl reduction with silanes. Full characterization of the phosphirenium ions i...

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Detalles Bibliográficos
Autores principales: Gasperini, Danila, Neale, Samuel E., Mahon, Mary F., Macgregor, Stuart A., Webster, Ruth L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8495902/
https://www.ncbi.nlm.nih.gov/pubmed/34631226
http://dx.doi.org/10.1021/acscatal.1c01133