Nonplanar Tub-Shaped Benzocyclooctatetraenes via Halogen-Radical Ring Opening of Dihydrobiphenylenes

[Image: see text] A novel tandem Ru-catalyzed [2+2+2] cycloaddition of arylenynes to dihydrobiphenylenes followed by halogen-radical ring opening has been developed for the construction of tub-shaped halogenated benzocyclooctatetraenes (bCOT’s). Cross-couplings and Diels–Alder reactions of the bromi...

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Detalles Bibliográficos
Autores principales: Bello-García, Jesús, Padín, Damián, Varela, Jesús A., Saá, Carlos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8499027/
https://www.ncbi.nlm.nih.gov/pubmed/34228464
http://dx.doi.org/10.1021/acs.orglett.1c01881

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8499027/
https://www.ncbi.nlm.nih.gov/pubmed/34228464
http://dx.doi.org/10.1021/acs.orglett.1c01881

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