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High Site Selectivity in Electrophilic Aromatic Substitutions: Mechanism of C–H Thianthrenation

[Image: see text] The introduction of thianthrene as a linchpin has proven to be a versatile strategy for the C–H functionalization of aromatic compounds, featuring a broad scope and fast diversification. The synthesis of aryl thianthrenium salts has displayed an unusually high para regioselectivity...

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Detalles Bibliográficos
Autores principales: Juliá, Fabio, Shao, Qianzhen, Duan, Meng, Plutschack, Matthew B., Berger, Florian, Mateos, Javier, Lu, Chenxi, Xue, Xiao-Song, Houk, K. N., Ritter, Tobias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8499029/
https://www.ncbi.nlm.nih.gov/pubmed/34546749
http://dx.doi.org/10.1021/jacs.1c06281