cis-1,4 Selective Coordination Polymerization of 1,3-Butadiene and Copolymerization with Polar 2-(4-Methoxyphenyl)-1,3-butadiene by Acenaphthene-Based α-Diimine Cobalt Complexes Featuring Intra-Ligand π-π Stacking Interactions

Highly cis-1,4 selective (up to 98%) coordination–insertion polymerization of 1,3-butadiene (BD) has been achieved herein using acenaphthene-based α-diimine cobalt complexes. Due to the presence of intra-ligand π-π stacking interactions, the complexes revealed high thermostability, affording polybut...

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Detalles Bibliográficos
Autores principales: Wang, Beibei, Liu, Heng, Tang, Tao, Zhang, Xuequan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8512132/
https://www.ncbi.nlm.nih.gov/pubmed/34641145
http://dx.doi.org/10.3390/polym13193329

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8512132/
https://www.ncbi.nlm.nih.gov/pubmed/34641145
http://dx.doi.org/10.3390/polym13193329

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