C–H oxidation in fluorenyl benzoates does not proceed through a stepwise pathway: revisiting asynchronous proton-coupled electron transfer

2-Fluorenyl benzoates were recently shown to undergo C–H bond oxidation through intramolecular proton transfer coupled with electron transfer to an external oxidant. Kinetic analysis revealed unusual rate-driving force relationships. Our analysis indicated a mechanism of multi-site concerted proton–...

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Detalles Bibliográficos
Autores principales: Coste, Scott C., Brezny, Anna C., Koronkiewicz, Brian, Mayer, James M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8513817/
https://www.ncbi.nlm.nih.gov/pubmed/34745543
http://dx.doi.org/10.1039/d1sc03344a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8513817/
https://www.ncbi.nlm.nih.gov/pubmed/34745543
http://dx.doi.org/10.1039/d1sc03344a

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