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The mechanism of oxidative addition of Pd(0) to Si–H bonds: electronic effects, reaction mechanism, and hydrosilylation

The oxidative addition of Pd to Si–H bonds is a crucial step in a variety of catalytic applications, and many aspects of this reaction are poorly understood. One important yet underexplored aspect is the electronic effect of silane substituents on reactivity. Herein we describe a systematic investig...

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Detalles Bibliográficos
Autores principales: Hurst, Michael R., Zakharov, Lev N., Cook, Amanda K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8513848/
https://www.ncbi.nlm.nih.gov/pubmed/34745535
http://dx.doi.org/10.1039/d1sc04419b