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Substituted aromatic pentaphosphole ligands – a journey across the p-block

The functionalization of pentaphosphaferrocene [Cp*Fe(η(5)-P(5))] (1) with cationic group 13–17 electrophiles is shown to be a general synthetic strategy towards P–E bond formation of unprecedented diversity. The products of these reactions are dinuclear [{Cp*Fe}(2){μ,η(5:5)-(P(5))(2)EX(2)}][TEF] (E...

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Detalles Bibliográficos
Autores principales: Riesinger, Christoph, Balázs, Gábor, Seidl, Michael, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8513863/
https://www.ncbi.nlm.nih.gov/pubmed/34745534
http://dx.doi.org/10.1039/d1sc04296c