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Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
Copper-catalyzed electrochemical direct chalcogenations of o-carboranes was established at room temperature. Thereby, a series of cage C-sulfenylated and C-selenylated o-carboranes anchored with valuable functional groups was accessed with high levels of position- and chemo-selectivity control. The...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8513870/ https://www.ncbi.nlm.nih.gov/pubmed/34745527 http://dx.doi.org/10.1039/d1sc02905c |