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Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature

Copper-catalyzed electrochemical direct chalcogenations of o-carboranes was established at room temperature. Thereby, a series of cage C-sulfenylated and C-selenylated o-carboranes anchored with valuable functional groups was accessed with high levels of position- and chemo-selectivity control. The...

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Detalles Bibliográficos
Autores principales: Yang, Long, Jei, Becky Bongsuiru, Scheremetjew, Alexej, Yuan, Binbin, Stückl, A. Claudia, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8513870/
https://www.ncbi.nlm.nih.gov/pubmed/34745527
http://dx.doi.org/10.1039/d1sc02905c