Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature

Copper-catalyzed electrochemical direct chalcogenations of o-carboranes was established at room temperature. Thereby, a series of cage C-sulfenylated and C-selenylated o-carboranes anchored with valuable functional groups was accessed with high levels of position- and chemo-selectivity control. The...

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Detalles Bibliográficos
Autores principales: Yang, Long, Jei, Becky Bongsuiru, Scheremetjew, Alexej, Yuan, Binbin, Stückl, A. Claudia, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8513870/
https://www.ncbi.nlm.nih.gov/pubmed/34745527
http://dx.doi.org/10.1039/d1sc02905c
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author Yang, Long
Jei, Becky Bongsuiru
Scheremetjew, Alexej
Yuan, Binbin
Stückl, A. Claudia
Ackermann, Lutz
author_facet Yang, Long
Jei, Becky Bongsuiru
Scheremetjew, Alexej
Yuan, Binbin
Stückl, A. Claudia
Ackermann, Lutz
author_sort Yang, Long
collection PubMed
description Copper-catalyzed electrochemical direct chalcogenations of o-carboranes was established at room temperature. Thereby, a series of cage C-sulfenylated and C-selenylated o-carboranes anchored with valuable functional groups was accessed with high levels of position- and chemo-selectivity control. The cupraelectrocatalysis provided efficient means to activate otherwise inert cage C–H bonds for the late-stage diversification of o-carboranes.
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spelling pubmed-85138702021-11-04 Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature Yang, Long Jei, Becky Bongsuiru Scheremetjew, Alexej Yuan, Binbin Stückl, A. Claudia Ackermann, Lutz Chem Sci Chemistry Copper-catalyzed electrochemical direct chalcogenations of o-carboranes was established at room temperature. Thereby, a series of cage C-sulfenylated and C-selenylated o-carboranes anchored with valuable functional groups was accessed with high levels of position- and chemo-selectivity control. The cupraelectrocatalysis provided efficient means to activate otherwise inert cage C–H bonds for the late-stage diversification of o-carboranes. The Royal Society of Chemistry 2021-09-01 /pmc/articles/PMC8513870/ /pubmed/34745527 http://dx.doi.org/10.1039/d1sc02905c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Yang, Long
Jei, Becky Bongsuiru
Scheremetjew, Alexej
Yuan, Binbin
Stückl, A. Claudia
Ackermann, Lutz
Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
title Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
title_full Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
title_fullStr Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
title_full_unstemmed Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
title_short Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
title_sort electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8513870/
https://www.ncbi.nlm.nih.gov/pubmed/34745527
http://dx.doi.org/10.1039/d1sc02905c
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