Change of Selectivity in C–H Functionalization Promoted by Nonheme Iron(IV)-oxo Complexes by the Effect of the N-hydroxyphthalimide HAT Mediator

[Image: see text] A kinetic analysis of the hydrogen atom transfer (HAT) reactions from a series of organic compounds to the iron(IV)-oxo complex [(N4Py)Fe(IV)(O)](2+) and to the phthalimide N-oxyl radical (PINO) has been carried out. The results indicate that a higher activating effect of α-heteroa...

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Detalles Bibliográficos
Autores principales: Di Berto Mancini, Marika, Del Gelsomino, Andrea, Di Stefano, Stefano, Frateloreto, Federico, Lapi, Andrea, Lanzalunga, Osvaldo, Olivo, Giorgio, Sajeva, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8515612/
https://www.ncbi.nlm.nih.gov/pubmed/34661000
http://dx.doi.org/10.1021/acsomega.1c03679

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8515612/
https://www.ncbi.nlm.nih.gov/pubmed/34661000
http://dx.doi.org/10.1021/acsomega.1c03679

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