Observability of Paramagnetic NMR Signals at over 10 000 ppm Chemical Shifts

We report an experimental observation of (31)P NMR resonances shifted by over 10 000 ppm (meaning percent range, and a new record for solutions), and similar (1)H chemical shifts, in an intermediate‐spin square planar ferrous complex [( tBu)(PNP)Fe‐H], where PNP is a carbazole‐based pincer ligand. U...

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Detalles Bibliográficos
Autores principales: Ott, Jonas C., Suturina, Elizaveta A., Kuprov, Ilya, Nehrkorn, Joscha, Schnegg, Alexander, Enders, Markus, Gade, Lutz H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518043/
https://www.ncbi.nlm.nih.gov/pubmed/34351041
http://dx.doi.org/10.1002/anie.202107944

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518043/
https://www.ncbi.nlm.nih.gov/pubmed/34351041
http://dx.doi.org/10.1002/anie.202107944

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