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Observability of Paramagnetic NMR Signals at over 10 000 ppm Chemical Shifts
We report an experimental observation of (31)P NMR resonances shifted by over 10 000 ppm (meaning percent range, and a new record for solutions), and similar (1)H chemical shifts, in an intermediate‐spin square planar ferrous complex [( tBu)(PNP)Fe‐H], where PNP is a carbazole‐based pincer ligand. U...
Autores principales: | Ott, Jonas C., Suturina, Elizaveta A., Kuprov, Ilya, Nehrkorn, Joscha, Schnegg, Alexander, Enders, Markus, Gade, Lutz H. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518043/ https://www.ncbi.nlm.nih.gov/pubmed/34351041 http://dx.doi.org/10.1002/anie.202107944 |
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