A Structural Diversity of Molecular Alkaline‐Earth‐Metal Polyphosphides: From Supramolecular Wheel to Zintl Ion

A series of molecular group 2 polyphosphides has been synthesized by using air‐stable [Cp*Fe(η(5)‐P(5))] (Cp*=C(5)Me(5)) or white phosphorus as polyphosphorus precursors. Different types of group 2 reagents such as organo‐magnesium, mono‐valent magnesium, and molecular calcium hydride complexes have...

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Detalles Bibliográficos
Autores principales: Yadav, Ravi, Weber, Martin, Singh, Akhil K., Münzfeld, Luca, Gramüller, Johannes, Gschwind, Ruth M., Scheer, Manfred, Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518058/
https://www.ncbi.nlm.nih.gov/pubmed/34403183
http://dx.doi.org/10.1002/chem.202102355

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518058/
https://www.ncbi.nlm.nih.gov/pubmed/34403183
http://dx.doi.org/10.1002/chem.202102355

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