Cargando…

A Structural Diversity of Molecular Alkaline‐Earth‐Metal Polyphosphides: From Supramolecular Wheel to Zintl Ion

A series of molecular group 2 polyphosphides has been synthesized by using air‐stable [Cp*Fe(η(5)‐P(5))] (Cp*=C(5)Me(5)) or white phosphorus as polyphosphorus precursors. Different types of group 2 reagents such as organo‐magnesium, mono‐valent magnesium, and molecular calcium hydride complexes have...

Descripción completa

Detalles Bibliográficos
Autores principales:	Yadav, Ravi, Weber, Martin, Singh, Akhil K., Münzfeld, Luca, Gramüller, Johannes, Gschwind, Ruth M., Scheer, Manfred, Roesky, Peter W.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518058/ https://www.ncbi.nlm.nih.gov/pubmed/34403183 http://dx.doi.org/10.1002/chem.202102355

Ejemplares similares

Snapshots of sequential polyphosphide rearrangement upon metallatetrylene addition
por: Sun, Xiaofei, et al.
Publicado: (2023)

The approach to 4d/4f-polyphosphides
por: Arleth, Nicholas, et al.
Publicado: (2015)

Application of the Redox‐Transmetalation Procedure to Access Divalent Lanthanide and Alkaline‐Earth NHC Complexes
por: Schwarz, Noah, et al.
Publicado: (2021)

The Valence Orbitals of the Alkaline‐Earth Atoms
por: Fernández, Israel, et al.
Publicado: (2020)

Alkali Metal Complexes of a Bis(diphenylphosphino)methane Functionalized Amidinate Ligand: Synthesis and Luminescence
por: Zovko, Christina, et al.
Publicado: (2021)

d/f‐Polypnictides Derived by Non‐Classical Ln(2+) Compounds: Synthesis, Small Molecule Activation and Optical Properties
por: Reinfandt, Niklas, et al.
Publicado: (2021)

Disilane Cleavage with Selected Alkali and Alkaline Earth Metal Salts
por: Santowski, Tobias, et al.
Publicado: (2019)

Probing the Validity of the Zintl−Klemm Concept for Alkaline-Metal Copper Tellurides by Means of Quantum-Chemical Techniques
por: Smid, Sabrina, et al.
Publicado: (2020)

Low-oxidation state cobalt–magnesium complexes: ion-pairing and reactivity
por: Kelly, John A., et al.
Publicado: (2021)

Filled skutterudite structure of europium ruthenium polyphosphide, EuRu(4)P(12)
por: Kagomiya, Isao, et al.
Publicado: (2010)

Special Issue: Advances in Zintl Phases
por: Kauzlarich, Susan M.
Publicado: (2019)

Tunable Porosities and Shapes of Fullerene-Like Spheres
por: Dielmann, Fabian, et al.
Publicado: (2015)

The layered polyphosphide Ag(3.73(4))Zn(2.27(4))P(16)
por: Köpf, Marianne, et al.
Publicado: (2012)

The Exchange Mechanism of Alkaline and Alkaline-Earth Ions in Zeolite N
por: Khosravi, Monireh, et al.
Publicado: (2019)

Molecular cyclo-P(3) complexes of the rare-earth elements via a one-pot reaction and selective reduction
por: Hauser, Adrian, et al.
Publicado: (2023)

Zintl Phases: From Curiosities to Impactful Materials
por: Kauzlarich, Susan M.
Publicado: (2023)

Reactivity of E(4) (E(4)=P(4), As(4), AsP(3)) towards Low‐Valent Al(I) and Ga(I) Compounds
por: Haimerl, Maria, et al.
Publicado: (2022)

Alkaline Earth Metal Template (Cross‐)Coupling Reactions with Hybrid Disila‐Crown Ether Analogues
por: Dankert, Fabian, et al.
Publicado: (2019)

The Potential of the Diphosphorus Complex [Cp(2)W(2)(CO)(4)(η(2)‐P(2))] as an Organometallic Connecter in Supramolecular Chemistry
por: Elsayed Moussa, Mehdi, et al.
Publicado: (2019)

Systematic DFT Studies on Binary Pseudo‐tetrahedral Zintl Anions: Relative Stabilities and Reactivities towards Protons, Trimethylsilyl Groups, and Iron Complex Fragments
por: Guggolz, Lukas, et al.
Publicado: (2020)

Enantiopure Calcium Iminophosphonamide Complexes: Synthesis, Photoluminescence, and Catalysis
por: Goswami, Bhupendra, et al.
Publicado: (2021)

Mixed Organometallic–Organic Hybrid Assemblies Based on the Diarsene Complex [Cp(2)Mo(2)(CO)(4)(μ,η(2)‐As(2))], Ag(I) Salts and N‐Donor Organic Molecules
por: Elsayed Moussa, Mehdi, et al.
Publicado: (2021)

Relaxation Dispersion NMR to Reveal Fast Dynamics in Brønsted Acid Catalysis: Influence of Sterics and H-Bond Strength on Conformations and Substrate Hopping
por: Lokesh, N., et al.
Publicado: (2019)

Bidentate substrate binding in Brønsted acid catalysis: structural space, hydrogen bonding and dimerization
por: Gramüller, Johannes, et al.
Publicado: (2022)

Enantioselective [2 + 2] Photocycloaddition via Iminium Ions: Catalysis by a Sensitizing Chiral Brønsted Acid
por: Pecho, Franziska, et al.
Publicado: (2021)

Brønsted acid catalysis – the effect of 3,3′-substituents on the structural space and the stabilization of imine/phosphoric acid complexes
por: Melikian, Maxime, et al.
Publicado: (2019)

From a nanoparticular solid-state material to molecular organo-f-element-polyarsenides
por: Reinfandt, Niklas, et al.
Publicado: (2022)

Alkaline earth metal vanadates as sodium-ion battery anodes
por: Xu, Xiaoming, et al.
Publicado: (2017)

Thermally Activated Delayed Fluorescence and Phosphorescence Quenching in Iminophosphonamide Copper and Zinc Complexes
por: Goswami, Bhupendra, et al.
Publicado: (2021)

A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes
por: Townrow, Oliver P. E., et al.
Publicado: (2020)

Alkaline earth metabolism in adult man
por: Commission Internationale de Protection contre les Radiations
Publicado: (1973)

Supramolecular Synthons: Will Giant Rigid Superspheres Do?
por: Peresypkina, Eugenia, et al.
Publicado: (2016)

Size‐Controlled Hapticity Switching in [Ln(C(9)H(9))(C(8)H(8))] Sandwiches
por: Tricoire, Maxime, et al.
Publicado: (2021)

Cationic Functionalisation by Phosphenium Ion Insertion
por: Riesinger, Christoph, et al.
Publicado: (2020)

The Archetypal Homoleptic Lanthanide Quadruple‐Decker—Synthesis, Mechanistic Studies, and Quantum Chemical Investigations
por: Münzfeld, Luca, et al.
Publicado: (2021)

Metal‐Bonded Redox‐Active Triarylamines and Their Interactions: Synthesis, Structure, and Redox Properties of Paddle‐Wheel Copper Complexes
por: Akintola, Oluseun, et al.
Publicado: (2019)

Zintl Phases as Reactive Precursors for Synthesis of Novel Silicon and Germanium-Based Materials
por: Beekman, Matt, et al.
Publicado: (2019)

Creation of two-dimensional layered Zintl phase by dimensional manipulation of crystal structure
por: Song, Junseong, et al.
Publicado: (2019)

Local order in a disordered Zintl phase boosts its thermoelectric performance
por: Ortner, Teresa S.
Publicado: (2021)

Alkaline-Earth-Catalyzed Dehydrocoupling of Amines and Boranes
por: Liptrot, David J, et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_p6d7chsklgdt2kc1fcckn05phh