Iron‐Catalyzed Cross‐Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols

Herein we disclose an iron‐catalyzed cross‐coupling reaction of propargyl ethers with Grignard reagents. The reaction was demonstrated to be stereospecific and allows for a facile preparation of optically active allenes via efficient chirality transfer. Various tri‐ and tetrasubstituted fluoroalkyl...

Descripción completa

Detalles Bibliográficos
Autores principales: Posevins, Daniels, Bermejo‐López, Aitor, Bäckvall, Jan‐E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518087/
https://www.ncbi.nlm.nih.gov/pubmed/34318557
http://dx.doi.org/10.1002/anie.202106742

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518087/
https://www.ncbi.nlm.nih.gov/pubmed/34318557
http://dx.doi.org/10.1002/anie.202106742

Ejemplares similares