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Application of the Redox‐Transmetalation Procedure to Access Divalent Lanthanide and Alkaline‐Earth NHC Complexes

Divalent lanthanide and alkaline‐earth complexes supported by N‐heterocyclic carbene (NHC) ligands have been accessed by redox‐transmetalation between air‐stable NHC‐AgI complexes and the corresponding metals. By using the small ligand 1,3‐dimethylimidazol‐2‐ylidene (IMe), two series of isostructura...

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Detalles Bibliográficos
Autores principales: Schwarz, Noah, Sun, Xiaofei, Yadav, Ravi, Köppe, Ralf, Simler, Thomas, Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518399/
https://www.ncbi.nlm.nih.gov/pubmed/34165229
http://dx.doi.org/10.1002/chem.202101923