Canopy Catalysts for Alkyne Metathesis: Investigations into a Bimolecular Decomposition Pathway and the Stability of the Podand Cap

Molybdenum alkylidyne complexes with a trisilanolate podand ligand framework (“canopy catalysts”) are the arguably most selective catalysts for alkyne metathesis known to date. Among them, complex 1 a endowed with a fence of lateral methyl substituents on the silicon linkers is the most reactive, al...

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Detalles Bibliográficos
Autores principales: Hillenbrand, Julius, Korber, J. Nepomuk, Leutzsch, Markus, Nöthling, Nils, Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518412/
https://www.ncbi.nlm.nih.gov/pubmed/34293239
http://dx.doi.org/10.1002/chem.202102080

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518412/
https://www.ncbi.nlm.nih.gov/pubmed/34293239
http://dx.doi.org/10.1002/chem.202102080

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