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Rapid and Direct Photocatalytic C(sp(3))−H Acylation and Arylation in Flow

Herein, we report a photocatalytic procedure that enables the acylation/arylation of unfunctionalized alkyl derivatives in flow. The method exploits the ability of the decatungstate anion to act as a hydrogen atom abstractor and produce nucleophilic carbon‐centered radicals that are intercepted by a...

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Detalles Bibliográficos
Autores principales: Mazzarella, Daniele, Pulcinella, Antonio, Bovy, Loïc, Broersma, Rémy, Noël, Timothy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518495/
https://www.ncbi.nlm.nih.gov/pubmed/34329531
http://dx.doi.org/10.1002/anie.202108987