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Spectroscopic Characterization of a Reactive [Cu(2)(μ‐OH)(2)](2+) Intermediate in Cu/TEMPO Catalyzed Aerobic Alcohol Oxidation Reaction

Cu(I)/TEMPO (TEMPO=2,2,6,6‐tetramethylpiperidinyloxyl) catalyst systems are versatile catalysts for aerobic alcohol oxidation reactions to selectively yield aldehydes. However, several aspects of the mechanism are yet unresolved, mainly because of the lack of identification of any reactive intermedi...

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Detalles Bibliográficos
Autores principales: Warm, Katrin, Tripodi, Guilherme, Andris, Erik, Mebs, Stefan, Kuhlmann, Uwe, Dau, Holger, Hildebrandt, Peter, Roithová, Jana, Ray, Kallol
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518518/
https://www.ncbi.nlm.nih.gov/pubmed/34309168
http://dx.doi.org/10.1002/anie.202108442