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Spectroscopic Characterization of a Reactive [Cu(2)(μ‐OH)(2)](2+) Intermediate in Cu/TEMPO Catalyzed Aerobic Alcohol Oxidation Reaction
Cu(I)/TEMPO (TEMPO=2,2,6,6‐tetramethylpiperidinyloxyl) catalyst systems are versatile catalysts for aerobic alcohol oxidation reactions to selectively yield aldehydes. However, several aspects of the mechanism are yet unresolved, mainly because of the lack of identification of any reactive intermedi...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518518/ https://www.ncbi.nlm.nih.gov/pubmed/34309168 http://dx.doi.org/10.1002/anie.202108442 |