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Stereospecific on‐Surface Cyclodehydrogenation of Bishelicenes: Preservation of Handedness from Helical to Planar Chirality

Flattening helices while keeping the handedness: On‐surface cyclodehydrogenation of bishelicene enantiomers leads stereospecifically to (M,M) and (P,P) chiral planar polyaromatic hydrocarbons. This is followed by their homochiral aggregation into a 2D conglomerate. Thermally induced cyclodehydrogena...

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Detalles Bibliográficos
Autores principales: Irziqat, Bahaaeddin, Cebrat, Aleksandra, Baljozović, Miloš, Martin, Kévin, Parschau, Manfred, Avarvari, Narcis, Ernst, Karl‐Heinz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518606/
https://www.ncbi.nlm.nih.gov/pubmed/34387926
http://dx.doi.org/10.1002/chem.202102069