Germyliumylidene: A Versatile Low Valent Group 14 Catalyst

Bis‐NHC stabilized germyliumylidenes [RGe(NHC)(2)](+) are typically Lewis basic (LB) in nature, owing to their lone pair and coordination of two NHCs to the vacant p‐orbitals of the germanium center. However, they can also show Lewis acidity (LA) via Ge−C(NHC) σ* orbital. Utilizing this unique elect...

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Detalles Bibliográficos
Autores principales: Sarkar, Debotra, Dutta, Sayan, Weetman, Catherine, Schubert, Emeric, Koley, Debasis, Inoue, Shigeyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518661/
https://www.ncbi.nlm.nih.gov/pubmed/34171132
http://dx.doi.org/10.1002/chem.202102233

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518661/
https://www.ncbi.nlm.nih.gov/pubmed/34171132
http://dx.doi.org/10.1002/chem.202102233

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