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Cation Ordering and Exsolution in Copper‐Containing Forms of the Flexible Zeolite Rho (Cu,M‐Rho; M=H, Na) and Their Consequences for CO(2) Adsorption

The flexibility of the zeolite Rho framework offers great potential for tunable molecular sieving. The fully copper‐exchanged form of Rho and mixed Cu,H‐ and Cu,Na‐forms have been prepared. EPR spectroscopy reveals that Cu(2+) ions are present in the dehydrated forms and Rietveld refinement shows th...

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Detalles Bibliográficos
Autores principales: Lozinska, Magdalena M., Jamieson, Sophie, Verbraeken, Maarten C., Miller, David N., Bode, Bela E., Murray, Claire A., Brandani, Stefano, Wright, Paul A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518693/
https://www.ncbi.nlm.nih.gov/pubmed/34213033
http://dx.doi.org/10.1002/chem.202101664