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Base‐Activated Latent Heteroaromatic Sulfinates as Nucleophilic Coupling Partners in Palladium‐Catalyzed Cross‐Coupling Reactions

Heteroaromatic sulfinates are effective nucleophilic reagents in Pd(0)‐catalyzed cross‐coupling reactions with aryl halides. However, metal sulfinate salts can be challenging to purify, solubilize in reaction media, and are not tolerant to multi‐step transformations. Here we introduce base‐activated...

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Detalles Bibliográficos
Autores principales: Cook, Xinlan A. F., Pantaine, Loïc R. E., Blakemore, David C., Moses, Ian B., Sach, Neal W., Shavnya, Andre, Willis, Michael C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518705/
https://www.ncbi.nlm.nih.gov/pubmed/34342107
http://dx.doi.org/10.1002/anie.202109146