Non‐conventional Behavior of a 2,1‐Benzazaphosphole: Heterodiene or Hidden Phosphinidene?

The titled 2,1‐benzazaphosphole (1) (i. e. ArP, where Ar=2‐(DippN=CH)C(6)H(4), Dipp=2,6‐iPr(2)C(6)H(3)) showed a spectacular reactivity behaving both as a reactive heterodiene in hetero‐Diels‐Alder (DA) reactions or as a hidden phosphinidene in the coordination toward selected transition metals (TMs...

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Detalles Bibliográficos
Autores principales: Kremláček, Vít, Kertész, Erik, Benkő, Zoltán, Erben, Milan, Jirásko, Robert, Růžička, Aleš, Jambor, Roman, Dostál, Libor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518707/
https://www.ncbi.nlm.nih.gov/pubmed/34096106
http://dx.doi.org/10.1002/chem.202101686

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518707/
https://www.ncbi.nlm.nih.gov/pubmed/34096106
http://dx.doi.org/10.1002/chem.202101686

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