Electro‐mediated PhotoRedox Catalysis for Selective C(sp(3))–O Cleavages of Phosphinated Alcohols to Carbanions

We report a novel example of electro‐mediated photoredox catalysis (e‐PRC) in the reductive cleavage of C(sp(3))−O bonds of phosphinated alcohols to alkyl carbanions. As well as deoxygenations, olefinations are reported which are E‐selective and can be made Z‐selective in a tandem reduction/photosen...

Descripción completa

Detalles Bibliográficos
Autores principales: Tian, Xianhai, Karl, Tobias A., Reiter, Sebastian, Yakubov, Shahboz, de Vivie‐Riedle, Regina, König, Burkhard, Barham, Joshua P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518744/
https://www.ncbi.nlm.nih.gov/pubmed/34165861
http://dx.doi.org/10.1002/anie.202105895

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518744/
https://www.ncbi.nlm.nih.gov/pubmed/34165861
http://dx.doi.org/10.1002/anie.202105895

Ejemplares similares