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Electro‐mediated PhotoRedox Catalysis for Selective C(sp(3))–O Cleavages of Phosphinated Alcohols to Carbanions
We report a novel example of electro‐mediated photoredox catalysis (e‐PRC) in the reductive cleavage of C(sp(3))−O bonds of phosphinated alcohols to alkyl carbanions. As well as deoxygenations, olefinations are reported which are E‐selective and can be made Z‐selective in a tandem reduction/photosen...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518744/ https://www.ncbi.nlm.nih.gov/pubmed/34165861 http://dx.doi.org/10.1002/anie.202105895 |