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Redox Isomerism in the S(3) State of the Oxygen‐Evolving Complex Resolved by Coupled Cluster Theory

The electronic and geometric structures of the water‐oxidizing complex of photosystem II in the steps of the catalytic cycle that precede dioxygen evolution remain hotly debated. Recent structural and spectroscopic investigations support contradictory redox formulations for the active‐site Mn(4)CaO(...

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Detalles Bibliográficos
Autores principales: Drosou, Maria, Pantazis, Dimitrios A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518824/
https://www.ncbi.nlm.nih.gov/pubmed/34288176
http://dx.doi.org/10.1002/chem.202101567