Cycloadditions with a Stable Charge‐Separated Cyclobutadiene‐Type Amido‐Substituted Silicon Ring Compound

Reductive debromination of {N(SiMe(3))(2)}SiBr(3) with Rieke magnesium results in the formation of the five‐vertex silicon cluster with one bromine substituent Si(5){N(SiMe(3))(2)}(5)Br, 1, and the cyclobutadiene analogue 2 in a 1:1 ratio. The latter features a planar four‐membered silicon ring with...

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Detalles Bibliográficos
Autores principales: Keuter, Jan, Hepp, Alexander, Daniliuc, Constantin G., Feldt, Milica, Lips, Felicitas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518912/
https://www.ncbi.nlm.nih.gov/pubmed/34255419
http://dx.doi.org/10.1002/anie.202104341

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518912/
https://www.ncbi.nlm.nih.gov/pubmed/34255419
http://dx.doi.org/10.1002/anie.202104341

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