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Cycloadditions with a Stable Charge‐Separated Cyclobutadiene‐Type Amido‐Substituted Silicon Ring Compound
Reductive debromination of {N(SiMe(3))(2)}SiBr(3) with Rieke magnesium results in the formation of the five‐vertex silicon cluster with one bromine substituent Si(5){N(SiMe(3))(2)}(5)Br, 1, and the cyclobutadiene analogue 2 in a 1:1 ratio. The latter features a planar four‐membered silicon ring with...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518912/ https://www.ncbi.nlm.nih.gov/pubmed/34255419 http://dx.doi.org/10.1002/anie.202104341 |