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Steric Hindrance Drives the Boron‐Initiated Polymerization of Dienyltriphenylarsonium Ylides to Photoluminescent C5‐Polymers
A series of alkyl‐subsituted dienyltriphenylarsonium ylides were synthesized and used as monomers in borane‐initiated polymerization to obtain practically pure C5‐polymers (main‐chain grows by five carbon atoms at a time). The impact of triethylborane (Et(3)B), tributylborane (Bu(3)B), tri‐sec‐butyl...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518972/ https://www.ncbi.nlm.nih.gov/pubmed/34387919 http://dx.doi.org/10.1002/anie.202109190 |