In‐Fjord Substitution in Expanded Helicenes: Effects of the Insert on the Inversion Barrier and Helical Pitch

A series of expanded helicenes of different sizes and shapes incorporating phenyl‐ and biphenyl‐substituents at the deepest part of their fjord have been synthesized via sequential Au‐catalyzed hydroarylation of appropriately designed diynes, and their racemization barriers have been calculated empl...

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Detalles Bibliográficos
Autores principales: Suárez‐Pantiga, Samuel, Redero, Pablo, Aniban, Xaiza, Simon, Martin, Golz, Christopher, Mata, Ricardo A., Alcarazo, Manuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8519012/
https://www.ncbi.nlm.nih.gov/pubmed/34288171
http://dx.doi.org/10.1002/chem.202102585

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8519012/
https://www.ncbi.nlm.nih.gov/pubmed/34288171
http://dx.doi.org/10.1002/chem.202102585

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