Atypical and Asymmetric 1,3‐P,N Ligands: Synthesis, Coordination and Catalytic Performance of Cycloiminophosphanes

Novel seven‐membered cyclic imine‐based 1,3‐P,N ligands were obtained by capturing a Beckmann nitrilium ion intermediate generated in situ from cyclohexanone with benzotriazole, and then displacing it by a secondary phosphane under triflic acid promotion. These “cycloiminophosphanes” possess flexibl...

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Detalles Bibliográficos
Autores principales: Rong, Mark K., Holtrop, Flip, Bobylev, Eduard O., Nieger, Martin, Ehlers, Andreas W., Slootweg, J. Chris, Lammertsma, Koop
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8519111/
https://www.ncbi.nlm.nih.gov/pubmed/34403555
http://dx.doi.org/10.1002/chem.202101921

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8519111/
https://www.ncbi.nlm.nih.gov/pubmed/34403555
http://dx.doi.org/10.1002/chem.202101921

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