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Atypical and Asymmetric 1,3‐P,N Ligands: Synthesis, Coordination and Catalytic Performance of Cycloiminophosphanes
Novel seven‐membered cyclic imine‐based 1,3‐P,N ligands were obtained by capturing a Beckmann nitrilium ion intermediate generated in situ from cyclohexanone with benzotriazole, and then displacing it by a secondary phosphane under triflic acid promotion. These “cycloiminophosphanes” possess flexibl...
Autores principales: | Rong, Mark K., Holtrop, Flip, Bobylev, Eduard O., Nieger, Martin, Ehlers, Andreas W., Slootweg, J. Chris, Lammertsma, Koop |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8519111/ https://www.ncbi.nlm.nih.gov/pubmed/34403555 http://dx.doi.org/10.1002/chem.202101921 |
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