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Reversible and Irreversible [2+2] Cycloaddition Reactions of Heteroallenes to a Gallaphosphene

[2+2] Cycloaddition reactions of gallaphosphene L(Cl)GaPGaL 1 (L=HC[C(Me)N(2,6‐i‐Pr(2)C(6)H(3))](2)) with carbodiimides [C(NR)(2); R=i‐Pr, Cy] and isocyanates [RNCO; R=Et, i‐Pr, Cy] yielded four‐membered metallaheterocycles LGa(Cl)P[μ‐C(X)NR]GaL (X=NR, R=i‐Pr 2, Cy 3; X=O, R=Et 4, i‐Pr 5, Cy 6). Com...

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Detalles Bibliográficos
Autores principales: Sharma, Mahendra K., Wölper, Christoph, Haberhauer, Gebhard, Schulz, Stephan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8519123/
https://www.ncbi.nlm.nih.gov/pubmed/34324782
http://dx.doi.org/10.1002/anie.202108370