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Reversible and Irreversible [2+2] Cycloaddition Reactions of Heteroallenes to a Gallaphosphene
[2+2] Cycloaddition reactions of gallaphosphene L(Cl)GaPGaL 1 (L=HC[C(Me)N(2,6‐i‐Pr(2)C(6)H(3))](2)) with carbodiimides [C(NR)(2); R=i‐Pr, Cy] and isocyanates [RNCO; R=Et, i‐Pr, Cy] yielded four‐membered metallaheterocycles LGa(Cl)P[μ‐C(X)NR]GaL (X=NR, R=i‐Pr 2, Cy 3; X=O, R=Et 4, i‐Pr 5, Cy 6). Com...
Autores principales: | Sharma, Mahendra K., Wölper, Christoph, Haberhauer, Gebhard, Schulz, Stephan |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8519123/ https://www.ncbi.nlm.nih.gov/pubmed/34324782 http://dx.doi.org/10.1002/anie.202108370 |
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