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Conformer-specific polar cycloaddition of dibromobutadiene with trapped propene ions

Diels–Alder cycloadditions are efficient routes for the synthesis of cyclic organic compounds. There has been a long-standing discussion whether these reactions proceed via stepwise or concerted mechanisms. Here, we adopt an experimental approach to explore the mechanism of the model polar cycloaddi...

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Detalles Bibliográficos
Autores principales: Kilaj, Ardita, Wang, Jia, Straňák, Patrik, Schwilk, Max, Rivero, Uxía, Xu, Lei, von Lilienfeld, O. Anatole, Küpper, Jochen, Willitsch, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8523519/
https://www.ncbi.nlm.nih.gov/pubmed/34663806
http://dx.doi.org/10.1038/s41467-021-26309-5