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Exploiting Continuous Processing for Challenging Diazo Transfer and Telescoped Copper-Catalyzed Asymmetric Transformations

[Image: see text] Generation and use of triflyl azide in flow enables efficient synthesis of a range of α-diazocarbonyl compounds, including α-diazoketones, α-diazoamides, and an α-diazosulfonyl ester, via both Regitz-type diazo transfer and deacylative/debenzoylative diazo-transfer processes with e...

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Detalles Bibliográficos
Autores principales: Crowley, Daniel C., Brouder, Thomas A., Kearney, Aoife M., Lynch, Denis, Ford, Alan, Collins, Stuart G., Maguire, Anita R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8524431/
https://www.ncbi.nlm.nih.gov/pubmed/34379975
http://dx.doi.org/10.1021/acs.joc.1c01310