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Speciation of Transition-Metal-Substituted Keggin-Type Silicotungstates Affected by the Co-crystallization Conditions with Proteinase K
[Image: see text] We report on the synthesis of the tetrasubstituted sandwich-type Keggin silicotungstates as the pure Na salts Na(14)[(A-α-SiW(10)O(37))(2){Co(4)(OH)(2)(H(2)O)(2)}]·37H(2)O (Na{SiW(10)Co(2)}(2)) and Na(14)[(A-α-SiW(10)O(37))(2){Ni(4)(OH)(2)(H(2)O)(2)}]·77.5H(2)O (Na{SiW(10)Ni(2)}(2)...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8527451/ https://www.ncbi.nlm.nih.gov/pubmed/34529407 http://dx.doi.org/10.1021/acs.inorgchem.1c02005 |