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Speciation of Transition-Metal-Substituted Keggin-Type Silicotungstates Affected by the Co-crystallization Conditions with Proteinase K

[Image: see text] We report on the synthesis of the tetrasubstituted sandwich-type Keggin silicotungstates as the pure Na salts Na(14)[(A-α-SiW(10)O(37))(2){Co(4)(OH)(2)(H(2)O)(2)}]·37H(2)O (Na{SiW(10)Co(2)}(2)) and Na(14)[(A-α-SiW(10)O(37))(2){Ni(4)(OH)(2)(H(2)O)(2)}]·77.5H(2)O (Na{SiW(10)Ni(2)}(2)...

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Detalles Bibliográficos
Autores principales: Breibeck, Joscha, Tanuhadi, Elias, Gumerova, Nadiia I., Giester, Gerald, Prado-Roller, Alexander, Rompel, Annette
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8527451/
https://www.ncbi.nlm.nih.gov/pubmed/34529407
http://dx.doi.org/10.1021/acs.inorgchem.1c02005

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