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Mesoionic Carbenes in Low- to High-Valent Vanadium Chemistry

[Image: see text] We report the synthesis of vanadium(V) oxo complex 1 with a pincer-type dianionic mesoionic carbene (MIC) ligand L(1) and the general formula [VOCl(L(1))]. A comparison of the structural (SC-XRD), electronic (UV–vis), and electrochemical (cyclic voltammetry) properties of 1 with th...

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Detalles Bibliográficos
Autores principales: Neururer, Florian R., Liu, Shenyu, Leitner, Daniel, Baltrun, Marc, Fisher, Katherine R., Kopacka, Holger, Wurst, Klaus, Daumann, Lena J., Munz, Dominik, Hohloch, Stephan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8527456/
https://www.ncbi.nlm.nih.gov/pubmed/34590834
http://dx.doi.org/10.1021/acs.inorgchem.1c02087