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Mesoionic Carbenes in Low- to High-Valent Vanadium Chemistry
[Image: see text] We report the synthesis of vanadium(V) oxo complex 1 with a pincer-type dianionic mesoionic carbene (MIC) ligand L(1) and the general formula [VOCl(L(1))]. A comparison of the structural (SC-XRD), electronic (UV–vis), and electrochemical (cyclic voltammetry) properties of 1 with th...
Autores principales: | Neururer, Florian R., Liu, Shenyu, Leitner, Daniel, Baltrun, Marc, Fisher, Katherine R., Kopacka, Holger, Wurst, Klaus, Daumann, Lena J., Munz, Dominik, Hohloch, Stephan |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8527456/ https://www.ncbi.nlm.nih.gov/pubmed/34590834 http://dx.doi.org/10.1021/acs.inorgchem.1c02087 |
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